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Can you show a picture of the bucket - what material is it? This is - IMO - not a temp/salinity/pH problem. Can be a NH3 problem but I would check the bucket first and change it to small aquarium instead.5g buckets is my option...
Tap water or rodi, is he using conditioner?If they’re dying within 24 hours then ammonia isn’t the problem. I’d check salinity and pH of your tank and the LFS. Its either an acclimation issue or stress.
1.022 seems a little low, but should be tolerable for a healthy fish.
FWIW, my success with QT went up dramatically when I added lots of plastic plants to break up the sight line and offer hiding spots. It reduces stress.
I would replace your air stone with a sponge filter. You can run the sponge filter in your sump for a month to initially establish bacteria in it. You can pick up a 10 gallon tank for cheap as well. You want to be able to observe your fish while they are in Quarantine. Test your QT like you would your display to make sure it has cycled before adding fish.
Sponge Filter Aquatics
Sponge Filters are great to have on hand for quarantine tanks, hospital tanks, and really any other time you may have a temporary tank set up to hold livestock. By hooking an air pump up to the sponge filter, and placing at the bottom of the aquarium, water will be drawn into the sponge allowing...www.bulkreefsupply.com
Petco has a 10 gallon for $10 right now: