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Is there some enzyme that eats detritus otherwise I probably need to do a physical rip clean at some point
Freshly dead algae you could say might be aided in decomposition by the enzyme cellulase.My personal opinion is that it breaks down and goes inert in time
Some aquarium products claim it, or claim to add microbes that can make it.
Something that's been in the tank a long time has already had essentially all available nutrition pulled out and it would be hard for any new addition to "break it down".
If you don't like the look of old piles of detritus that have sat there for weeks.... suck it out.
Freshly dead stuff may offer a better target for treatment - it could release nutrients relevant to nuisance growth. A carbon dose can be a measure against that.