Soda ash is fine for what you're doing, chemically it's the right pick if you want to nudge alk without dragging pH down. But I'd ask one question first: when's the last time you bumped your AFR dose rate?
AFR is balanced, so if your alk is consistently sitting at 7.4–7.8 instead of 8.5+, the simplest read is that you're under-dosing AFR overall. Your corals are probably consuming slightly more than the bottle's "standard" rate suggests. The fix is to step the AFR up by 10–15% and re-test in a week. If alk lands where you want, no second doser needed!
If you've already pushed AFR up and alk still won't climb, then yes, second doser with soda ash, dosed separately.
A few notes if you go that route:
- Mix soda ash at ~70 g/L RO/DI. One mL of that solution moves ~0.014 dKH per US gallon of net tank water. So bumping a 100 gal from 7.6 to 8.4 (a 0.8 dKH lift) is ~57 mL of stock solution total, spread across 3–4 days at ≤1 dKH/day.
- Drip it slowly (most people split into 6–12 doses/day) rather than slug it. Soda ash will spike pH locally if dumped.
- Dose it in a high-flow area, not next to the AFR drip point.