Redfield might be a decent starting point for dosing both N and P if neither are detectable. Trial and error will tell you over time what ratio works best.
Can you explain what you mean? The red field ratio is the content of the elements in the organisms (as you stated) - the interesting thing about the ratio was it's consistency across many if not all oceans. As I think you stated before - I also can't see why dosing anything based on the Redfield ratio would be helpful. As I understand it - it has very little to do with the contents of the water surrounding the phytoplankton.