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Yes. Many undesirable compounds are present in water purified by reverse osmosis that can only be removed by deionizing resins. These elements include, but are not limited to, copper, ammonium, silicates and phosphate.
Water quality is one of the most important components of a reef tank. I like saving a buck more than almost anyone else, but this is a bad place to do it.
I would not use 5 TDS water