Most kitchen and bath caulk has arsenic in it and will kill your tank inhabitants. Buy aquarium caulk. For small amounts most fish stores stock the small tubes. For larger projects order it online. Most large lumberyards sell dozens of types of caulk and yet few if any are aquarium safe. You have to get caulk that says aquarium use or food safe. Even some that say 100% silicone aren't safe to use. The tube you're holding up says mold free and that means it has an additive to kill algae. Most likely arsenic.