Ph of rodi water

HankstankXXL750

Valuable Member
View Badges
Joined
May 23, 2022
Messages
1,925
Reaction score
1,598
Location
Kearney
Rating - 100%
5   0   0
What you really need to know is what is your pH of freshly mixed water. The salt mix will change the pH. If it mixes to what you want there is no problem. Otherwise you might need to change the pH after mixing either through aeration or buffers.
 
OP
OP
trainbob

trainbob

Active Member
View Badges
Joined
May 29, 2021
Messages
230
Reaction score
221
Location
Stroudsburg
Rating - 0%
0   0   0
Thanks for your reply and the article. Now I know why s advocate a remineralization filter
 

Randy Holmes-Farley

Reef Chemist
View Badges
Joined
Sep 5, 2014
Messages
67,410
Reaction score
63,760
Location
Arlington, Massachusetts, United States
Rating - 0%
0   0   0
Thanks for your reply and the article. Now I know why s advocate a remineralization filte

I believe I have a much more accurate and useful answer to that question:

Reverse Osmosis/Deionization Systems to Purify Tap Water for Reef Aquaria by Randy Holmes-Farley - Reefkeeping.com

Final Effluent pH

Aside from the issues discussed above concerning the effluent’s pH when the DI resin becomes depleted, the final pH coming out of an RO/DI system should not significantly concern reef aquarists. Many aquarists with low pH problems have asked, for example, if their aquarium’s low pH may be caused by their replacing evaporated water with RO/DI water that they measure to have a pH below 7. In short, the answer is no, this is not a cause of low pH nor is it something to be generally concerned about, for the following reasons:

1. The pH of totally pure water is around 7 (with the exact value depending on temperature). As carbon dioxide from the atmosphere enters the water, the pH drops into the 6’s and even into the 5’s, depending on the amount of CO2. At saturation with the level of CO2 in normal (outside) air, the pH would be about 5.66. Indoor air often has even more CO2, and the pH can drop a bit lower, into the 5’s. Consequently, the pH of highly purified water coming from an RO/DI unit is expected to be in the pH 5-7 range.

2. The pH of highly purified water is not accurately measured by test kits, or by pH meters. There are several different reasons for this, including the fact that highly purified water has very little buffering capacity, so its pH is easily changed. Even the acidity or basicity of a pH test kit’s indicator dye is enough to alter pure water’s measured pH. As for pH meters, the probes themselves do not function well in the very low ionic strength of pure freshwater, and trace impurities on them can swing the pH around quite a bit.

3. The pH of the combination of two solutions does not necessarily reflect the average (not even a weighted average) of their two pH values. The final pH of a mixture may actually not even be between the pH’s of the two solutions when combined. Consequently, adding pH 7 pure water to pH 8.2 seawater may not even result in a pH below 8.2, but rather might be higher than 8.2 (for complex reasons relating to the acidity of bicarbonate in seawater vs. freshwater).
 

Jamie814

Active Member
View Badges
Joined
Mar 15, 2021
Messages
289
Reaction score
261
Location
43°17'29.7"N 91°47'49.0"W
Rating - 100%
1   0   0
I believe I have a much more accurate and useful answer to that question:

Reverse Osmosis/Deionization Systems to Purify Tap Water for Reef Aquaria by Randy Holmes-Farley - Reefkeeping.com

Final Effluent pH

Aside from the issues discussed above concerning the effluent’s pH when the DI resin becomes depleted, the final pH coming out of an RO/DI system should not significantly concern reef aquarists. Many aquarists with low pH problems have asked, for example, if their aquarium’s low pH may be caused by their replacing evaporated water with RO/DI water that they measure to have a pH below 7. In short, the answer is no, this is not a cause of low pH nor is it something to be generally concerned about, for the following reasons:

1. The pH of totally pure water is around 7 (with the exact value depending on temperature). As carbon dioxide from the atmosphere enters the water, the pH drops into the 6’s and even into the 5’s, depending on the amount of CO2. At saturation with the level of CO2 in normal (outside) air, the pH would be about 5.66. Indoor air often has even more CO2, and the pH can drop a bit lower, into the 5’s. Consequently, the pH of highly purified water coming from an RO/DI unit is expected to be in the pH 5-7 range.

2. The pH of highly purified water is not accurately measured by test kits, or by pH meters. There are several different reasons for this, including the fact that highly purified water has very little buffering capacity, so its pH is easily changed. Even the acidity or basicity of a pH test kit’s indicator dye is enough to alter pure water’s measured pH. As for pH meters, the probes themselves do not function well in the very low ionic strength of pure freshwater, and trace impurities on them can swing the pH around quite a bit.

3. The pH of the combination of two solutions does not necessarily reflect the average (not even a weighted average) of their two pH values. The final pH of a mixture may actually not even be between the pH’s of the two solutions when combined. Consequently, adding pH 7 pure water to pH 8.2 seawater may not even result in a pH below 8.2, but rather might be higher than 8.2 (for complex reasons relating to the acidity of bicarbonate in seawater vs. freshwater).
Great info, Thanks Randy!
 

Randy Holmes-Farley

Reef Chemist
View Badges
Joined
Sep 5, 2014
Messages
67,410
Reaction score
63,760
Location
Arlington, Massachusetts, United States
Rating - 0%
0   0   0
Here’s an article I found.

That article is filled with bogus misinformation. I’d suggest not reposting it at REEF2REEF unless you believe it is accurate and want to debate the pseudoscience in it.
 

TnFishwater98

Drink more fishwater there! And I still want more!
View Badges
Joined
Nov 7, 2017
Messages
6,544
Reaction score
8,453
Location
Nashville TN
Rating - 0%
0   0   0
I have just realized this also. I’ve never tested PH on my top of water before. However my son got an African Dwarf Frog and I told him we needed to transfer it from a .5 gallon to a 5 gallon tank. I’ve never done freshwater tanks besides the classic goldfish in a bowl when I was a kid. So I used my RO/Di water to cycle the tank. Obviously when testing PH tested at the low end of the scale. So this was also new info to me. So questions is , having low 5-6 ph top-off water will not affect the tanks Ph correct? Even if top off sensor goes in idle mode for some reason and you have to add a lot of top off water to correct the salinity ?
 
OP
OP
trainbob

trainbob

Active Member
View Badges
Joined
May 29, 2021
Messages
230
Reaction score
221
Location
Stroudsburg
Rating - 0%
0   0   0
Thanks Randy your response is greatly appreciated and it is good to know that my top off water is not adversely affecting the ph of the tank.
 

HankstankXXL750

Valuable Member
View Badges
Joined
May 23, 2022
Messages
1,925
Reaction score
1,598
Location
Kearney
Rating - 100%
5   0   0
That article is filled with bogus misinformation. I’d suggest not reposting it at REEF2REEF unless you believe it is accurate and want to debate the pseudoscience in it.
Thanks. I just did a quick look at the first part where it stated that pure water was 7 and RO/DI could quickly change to as low as 5 which is what the op was questioning. I should have read farther.
As you stated in a later post, the real factor is your pH post mix.
Thanks for the heads up.
 

Randy Holmes-Farley

Reef Chemist
View Badges
Joined
Sep 5, 2014
Messages
67,410
Reaction score
63,760
Location
Arlington, Massachusetts, United States
Rating - 0%
0   0   0
having low 5-6 ph top-off water will not affect the tanks Ph correct? Even if top off sensor goes in idle mode for some reason and you have to add a lot of top off water to correct the salinity ?

That is correct. :)
 

Reefing threads: Do you wear gear from reef brands?

  • I wear reef gear everywhere.

    Votes: 29 15.7%
  • I wear reef gear primarily at fish events and my LFS.

    Votes: 11 5.9%
  • I wear reef gear primarily for water changes and tank maintenance.

    Votes: 1 0.5%
  • I wear reef gear primarily to relax where I live.

    Votes: 24 13.0%
  • I don’t wear gear from reef brands.

    Votes: 108 58.4%
  • Other.

    Votes: 12 6.5%
Back
Top