You are correct. A good friend ran her 240 zeo tank with a Dkh of 7-8 and anything higher would cause her corals to get alk burn fast. I could get a frag from her though, and drop it right into my tank with a Dkh of 11 and the coral would be fine. I never could figure that out. Even when she ran zeo free with low alk her corals would not tolerate anything above about 8.5.
Alkalinity levels and requirements are not this mysterious.
Read (or re-read) some of Randy's work on the topic to alleviate that mystery! [emoji41][emoji106]
The folks running carbon dosing have some strange chemistry going on in their tanks-it's as simple as that.
For the rest of us, alkalinity stability (above 2.5 mEq/L) is the only real concern.
There doesn't seem to be a "harmful" upper limit. You don't really find it done anymore but if you look back through the history of reefing there are examples of successful tanks with astronomically high alkalinity. No "alk burn".