I’ve seen this sort of thing when a house was painted. The painters used some sort of alcohol based solvent either in prep or in the paint. The house smelled awful, and the tank despite being covered got cloudy and unhappy fast.
1) You have said you are dosing a lot of nitrate and phosphate, but that’s relative. What is it in PPM of each? I had a system that I dose on average 1 PPM for over a year without carbon dosing. The system simply consumed it. KNO3 and Mg(NO3)2 are both cheap in powder form.
2) Running the skimmer to distant/outside (preferred) or very heavily carbon filtered air prevents introducing alcohol via the skimmer, but it won’t take it out very efficiently (neither will changing water really). You’d like it to not get in via other routes either. Cover the sump and display with lids. Then plumb the air outlet vents from the skimmer lid to whichever has more area*concentration. This will run clean air through the skimmer, then the still pretty clean air through the space at the water surface. It’ll put that area at slight positive pressure which will keep the fumes out of the water.
1) You have said you are dosing a lot of nitrate and phosphate, but that’s relative. What is it in PPM of each? I had a system that I dose on average 1 PPM for over a year without carbon dosing. The system simply consumed it. KNO3 and Mg(NO3)2 are both cheap in powder form.
2) Running the skimmer to distant/outside (preferred) or very heavily carbon filtered air prevents introducing alcohol via the skimmer, but it won’t take it out very efficiently (neither will changing water really). You’d like it to not get in via other routes either. Cover the sump and display with lids. Then plumb the air outlet vents from the skimmer lid to whichever has more area*concentration. This will run clean air through the skimmer, then the still pretty clean air through the space at the water surface. It’ll put that area at slight positive pressure which will keep the fumes out of the water.