You could do that, or you could via KH supplement (take a stroll to Randy's forum here on R2R, he has plenty of information on how to do this with common household products) to slowly raise the tank .5-.7dkh per day. When you do water changes, you will want to test alkalinity to make sure it matches the tank otherwise you run the risk of undoing your daily dosing hard work :).
If you do not plan on running an ultra low nutrient system, you can move to a salt mix that mixes closer to your target or just manually up your NSW before changes. I use the aquaforest reef salt which mixes right about 7.7-8dkh for me so I don't have to worry about extra stuff during maintenance :).
As for dosing calcium, spread the dose out at least 20 minutes between adding the alk booster (baking soda, KH buffer, etc.) and calcium. you can always dose one in the morning and one in the evening. If they are too close together you risk precipitating calcium carbonate out of the aquarium and again, undoing all of your hard work.