You provide great information but IMO are over complicating it. OP just needs to raise his PH 0.3-0.4 overnight and when you're ask which one or the other, you look at the largest difference between the two. If OP already has issues with nutrients then obviously a refugium is out of the question. It really is that easy to answer OP's question. However, once you answer that question that's, how to best implement adding ALK to OP's tank without causing issues with their current 2-part dosing regime. That is where your information comes into play.
OP, if you're really looking for a simple answer to raising your PH without causing a disruption in your dosing regime, get a large (or a couple) Pothos or a Snake Plant next to the aquarium. I live in a fairly rural community but even I saw a large jump in PH when we started keeping house plants, and mine are only in the room adjacent to my aquarium. If you don't have a lot of windows in the room, you can always buy a $15 plant light from amazon and you'll be good to go. Worst comes to worst, if you don't see a change, at least you have some nice new decor!