Saltwater buckets - dirty at bottoy

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FOBbit

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I can't make my own water. I live in an apt. No space. So I buy salt and top off water from my local fish store.
When I'm done with my water changes I clean the buckets out, and notice a grey-ish film on the bottom. I just wipe it off with a paper towel. Buckets are either old salt, or ones I bought from the fish store.

Question is why? What is causing that?
 

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