Sodium Bisulfate to Reduce Alkalinity in New Salt Water or in Display Tanks

OP
OP
Randy Holmes-Farley

Randy Holmes-Farley

Reef Chemist
View Badges
Joined
Sep 5, 2014
Messages
67,421
Reaction score
63,782
Location
Arlington, Massachusetts, United States
Rating - 0%
0   0   0
By dosing in the aquarium....

Better to do it by water change.

But if you want to do it to a tank, I'd limit it to 0.1 dKh per day drop due to the pH lowering, unless you carefully monitor it and ensure it is not getting too low. A 1.4 dKh drop may drop the pH as low as 6.9, and that assumes you started at pH 8.1. I'd add it late afternoon when pH is highest.
 

BradB

Well-Known Member
View Badges
Joined
Aug 27, 2009
Messages
563
Reaction score
327
Location
Hudson
Rating - 0%
0   0   0
I don't understand this at all. Unless you pick a salt like Reef Crystals, where you are intentionally paying extra money for extra Alkalinity, Alkalinity is going to be close to NSW. For a 30% water change the extra Alkalinity is somewhere between completely irrelevant and slightly beneficial. If you do have an Acropora based tank, or other Alkalinity sensitive animals, you aren't going to change more than 30% of your water at once unless it is an emergency. When I do have a 3am 100% water change emergency, I am not going to be worried about acid or alkalinity.
 
OP
OP
Randy Holmes-Farley

Randy Holmes-Farley

Reef Chemist
View Badges
Joined
Sep 5, 2014
Messages
67,421
Reaction score
63,782
Location
Arlington, Massachusetts, United States
Rating - 0%
0   0   0
I don't understand this at all. Unless you pick a salt like Reef Crystals, where you are intentionally paying extra money for extra Alkalinity, Alkalinity is going to be close to NSW. For a 30% water change the extra Alkalinity is somewhere between completely irrelevant and slightly beneficial. If you do have an Acropora based tank, or other Alkalinity sensitive animals, you aren't going to change more than 30% of your water at once unless it is an emergency. When I do have a 3am 100% water change emergency, I am not going to be worried about acid or alkalinity.


It is not true that higher alk mixes cost more. Normal IO is among the cheapest and has alk higher than many would like.

Thus, if you want an 8 dKH mix, and don't want to pay more, mixing some acid into normal IO is an excellent choice that some folks have elected.

If you are maintaining 8 dKH and do a 30% water change with 11 dKH IO, alk rises to 8.9 dKH. Some folks consider that undesirable, especially if they have dosing set on a dosing pump.

As you can see from the two posts above yours, some folks have to deal with rising alk.
 
Last edited:

Browser

Community Member
View Badges
Joined
Dec 9, 2022
Messages
28
Reaction score
9
Location
Athens
Rating - 0%
0   0   0
@Randy Holmes-Farley I made a RODI dilution of sodium bisulfate capable of reducing my alk to my target.
I then set a daily dosage from 17:00 to 23:00 with amount equal to reduce my alk by 0.1.
I also check the ph not to be less that 7.9 which will stop my dosing.
If all goes well my alk target will be reached in 20-21 days.

My only concern is that a reduced ph will increase the dissolving rate (of what is seems to be disolving), and I am afraid that I will be caught in a perpetual situation. What do youbthink about that?
 
OP
OP
Randy Holmes-Farley

Randy Holmes-Farley

Reef Chemist
View Badges
Joined
Sep 5, 2014
Messages
67,421
Reaction score
63,782
Location
Arlington, Massachusetts, United States
Rating - 0%
0   0   0
@Randy Holmes-Farley I made a RODI dilution of sodium bisulfate capable of reducing my alk to my target.
I then set a daily dosage from 17:00 to 23:00 with amount equal to reduce my alk by 0.1.
I also check the ph not to be less that 7.9 which will stop my dosing.
If all goes well my alk target will be reached in 20-21 days.

My only concern is that a reduced ph will increase the dissolving rate (of what is seems to be disolving), and I am afraid that I will be caught in a perpetual situation. What do youbthink about that?

Well, let's see what happens. Your plan looks good to me. :)

For a while, don't put too much dosing solution in the reservoir in case somethign goes wrong and too much gets dosed. :)
 

BradB

Well-Known Member
View Badges
Joined
Aug 27, 2009
Messages
563
Reaction score
327
Location
Hudson
Rating - 0%
0   0   0
I don't understand your concern with knowledge that you can take or leave, like a lot of other products, but no one is trying to get you to use it.

It is not true that higher alk mixes cost more. Normal IO is among the cheapest and has alk higher than many would like.

Thus, if you want an 8 dKH mix, and don't want to pay more, mixing some acid into normal IO is an excellent choice that some folks have elected.

If you are maintaining 8 dKH and do a 30% water change with 11 dKH IO, alk rises to 8.9 dKH. Some folks consider that undesirable, especially if they have dosing set on a dosing pump.

As you can see from the two posts above yours, some folks have to deal with rising alk.

I am not complaining you put this out there. With 4 pages of comments, I assumed there was a useful reason, but I missed it.

I was mainly comparing Reef Crystals and IO, although there are other salts similar to Reef Crystals that seemed marketed towards people with stony corals who'd rather rely on water changes than dosing or calcium reactors. Buying Reef Crystals and complaining the Alkalinity is too high is reasonable. But then switching to IO is more reasonable than keeping Reef Crystals and adding acid. I rarely test my salt mix, but use IO and would be surprised if it was 11 dKH.

I aim for 10 dKH on paper, but struggle to keep 9 and never change more than 20% of my water except for emergencies. I can understand if you target 8 dKH, want to use IO and don't want fluctuations.
 

Browser

Community Member
View Badges
Joined
Dec 9, 2022
Messages
28
Reaction score
9
Location
Athens
Rating - 0%
0   0   0
You're welcome.

Happy Reefing. :)
Hello again.

Just to let you know how it goes..

Screenshot 2023-04-18 131030.png


It worked fine.
I checked the ph effect and did not seem to be to dramatic, so i increased the dosage during the day.
I controled the dosage checking the PH not to drop less than 7.9, and also my alk not to drop more than 8.3, when i stopped the dosing.
I consumed half the sodium sulfate solution of what i have calculated.

I am now checking the system to see if i will have an increase in alk again.

PS. I also make a 5lt water change daily.
 
Last edited:

gbroadbridge

2500 Club Member
View Badges
Joined
Mar 25, 2021
Messages
4,026
Reaction score
4,190
Location
Sydney, Australia
Rating - 0%
0   0   0
Hello again.

Just to let you know how it goes..

Screenshot 2023-04-18 131030.png


It worked fine.
I checked the ph effect and did not seem to be to dramatic, so i increased the dosage during the day.
I controled the dosage checking the PH not to drop less than 7.9, and also my alk not to drop more than 8.3, when i stopped the dosing.
I consumed half the sodium sulfate solution of what i have calculated.

I am now checking the system to see if i will have an increase in alk again.

PS. I also make a 5lt water change daily.
Thanks for posting that - saved for future reference
 
OP
OP
Randy Holmes-Farley

Randy Holmes-Farley

Reef Chemist
View Badges
Joined
Sep 5, 2014
Messages
67,421
Reaction score
63,782
Location
Arlington, Massachusetts, United States
Rating - 0%
0   0   0
Hello again.

Just to let you know how it goes..

Screenshot 2023-04-18 131030.png


It worked fine.
I checked the ph effect and did not seem to be to dramatic, so i increased the dosage during the day.
I controled the dosage checking the PH not to drop less than 7.9, and also my alk not to drop more than 8.3, when i stopped the dosing.
I consumed half the sodium sulfate solution of what i have calculated.

I am now checking the system to see if i will have an increase in alk again.

PS. I also make a 5lt water change daily.

Great, thanks for the update!
 

EricR

Valuable Member
View Badges
Joined
Jun 9, 2021
Messages
2,327
Reaction score
2,465
Location
California USA
Rating - 0%
0   0   0
Just wanted to say, "Thank you, Mr. Randy sir!" for this article. (Increasing alkalinity with no dosing is my issue that I now see is not unheard of for various reasons so now using this method for reduction)
...won't cloud this thread further
 
OP
OP
Randy Holmes-Farley

Randy Holmes-Farley

Reef Chemist
View Badges
Joined
Sep 5, 2014
Messages
67,421
Reaction score
63,782
Location
Arlington, Massachusetts, United States
Rating - 0%
0   0   0
Just wanted to say, "Thank you, Mr. Randy sir!" for this article. (Increasing alkalinity with no dosing is my issue that I now see is not unheard of for various reasons so now using this method for reduction)
...won't cloud this thread further

You're welcome. :)
 

c4haskett

Active Member
View Badges
Joined
May 10, 2021
Messages
136
Reaction score
183
Location
Windsor, VA
Rating - 0%
0   0   0
For what it's worth, I use IO Reef Crystals specifically for elevated calcium and magnesium. I prefer to run about 9 dKh. I have consistently used "hardware store" grade muriatic acid to a fresh batch of saltwater for about 2.5 years now. I always wait 24 hour to let excess c02 out and ph always returns to normal with medium to heavy flow pointed towards the surface of my reservoir. I've never noticed any ill effects or anything unusual after a water change. I've had the same jug of muriatic acid now for the entire 2.5 years I've had it.
 

nano reef

Valuable Member
View Badges
Joined
Dec 9, 2019
Messages
1,786
Reaction score
466
Rating - 0%
0   0   0
OP
OP
Randy Holmes-Farley

Randy Holmes-Farley

Reef Chemist
View Badges
Joined
Sep 5, 2014
Messages
67,421
Reaction score
63,782
Location
Arlington, Massachusetts, United States
Rating - 0%
0   0   0
I consumed half the sodium sulfate solution of what i have calculated.

I assume that is a typo and you mean sodium bisulfate? Sodium sulfate is a different chemical and is useless in relation to alkalinity.
 

Reefing threads: Do you wear gear from reef brands?

  • I wear reef gear everywhere.

    Votes: 37 15.9%
  • I wear reef gear primarily at fish events and my LFS.

    Votes: 13 5.6%
  • I wear reef gear primarily for water changes and tank maintenance.

    Votes: 1 0.4%
  • I wear reef gear primarily to relax where I live.

    Votes: 30 12.9%
  • I don’t wear gear from reef brands.

    Votes: 135 58.2%
  • Other.

    Votes: 16 6.9%
Back
Top