I have done freshwater most of my life but reef side it’s significantly more labor intensive.
There are enough different ways to accomplish a successful reef tank that IMO the hobby is as hard as we choose to make it.
Kalk is not one of the easier ways to maintain alkalinity. For one, it's not just an alk supplement....which is why your Ca levels are pegging your test kit. It can also cause quite large pH spikes which can cause issues for other things. It's quite hard to manage in most circumstances.
Regular water changes might be a better option for you. Reef Crystals has higher Ca, alk and Mg levels if your tank needs a stronger supplement than what comes with the standard Instant Ocean formula. The limit to watch out for is that you don't do too many water changes and lower nutrient levels too much. Eventually this is when folks add dosing of one kind or another to their arsenal.
An all in one product might be better...I've used Brightwell Liquid Reef and Elemental and Tropic Marin BioCalcium with good results under light demand scenarios. I guess you really can't get any simpler than BioCalcium – so maybe it would be the best for you.
If you are comfortable setting up some dosing pumps, then I've had great luck with varaious two-part and three-part dosing systems. ESV B-ionic is probably my favorite, and it comes as a very convenient two-part. But I've used Brightwell's equivalent and it's almost as good.
I have also used A LOT of Randy's Recipe #2 (using baking soda) and I think it's the standout best of all the DIY formulas. None are totally easy, but probably still easier than kalk. And they are all VERY economical. Magnesium chloride is the part I was never able to source locally tho.
Using kalk+vinegar is something you might want to look into if you DO intend to keep using kalk. Vinegar can take the edge off of that giant pH spike as well as getting higher rates of solubility. So it does simplify some aspects of using kalk, but then you have more things to manage with the vinegar blend and what else it can bean in your tank.
So it's still a pretty complicated system compared to a one-part or two-part option.
Just regular arm and hammer baking soda will work just fine from day Walmart? Assuming it has no additives, scented or whatever for soda ash?
Yep. If you shop around someplace around you probably sells the larger (7 pound?) bags. But the 1 pound standard boxes are also convenient since it's a pre-weighed pound and they are never expensive even when you pay full price.