Why Is Alk Rising?

Update: I added 15 grams of muriatic acid to 11 gallons of freshly made saltwater. Today, I changed half a gallon of the tank water with the 0 alk water. It dropped the ph down to 7.4 and the alkalinity is now around 8.5. Corals are not too happy.

Did I do something wrong? I put the new water in slowly and in a “high flow” area.
 
Update: I added 15 grams of muriatic acid to 11 gallons of freshly made saltwater. Today, I changed half a gallon of the tank water with the 0 alk water. It dropped the ph down to 7.4 and the alkalinity is now around 8.5. Corals are not too happy.

Did I do something wrong? I put the new water in slowly and in a “high flow” area.

You may have added a bit too much muriatic acid to the new salt water to see that large of an alk drop in the tank.

You should aerate the new water a lot to drive off CO2 before adding it. You should be able to bring to the pH to 7 or above.

Here’s a copy and paste of my recipe:

You can use muriatic acid or certain freshwater buffers to lower alk.
Both will lower pH similarly and a lot. There's no way around the pH lowering when reducing alkalinity. You do not want to add CO2. You want to remove CO2 from the tank via aeration.

For that reason, it is best to do it in water change water that is aerated to raise pH before using, or to do it very slowly in the tank (over many days).

The "acidity" (that being essentially negative alkalinity) of muriatic acid straight from the bottle is about 11,000 meq/L.

So adding 1/11,000 of the water volume as this acid will drop alkalinity by 1 meq/l (2.8 dKH).

I would not drop more than 1 dKH per day due to the big pH drop in a reef tank, but in new salt water it is fine.

You'll need to aerate well after adding the acid to blow off the excess CO2 and bring up the pH.
 

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