As for drilling the tank, the best way to know for sure is with the polarized sunglasses trick
@FrugalReeferJon linked above. Keep in mind that even if the bottom was tempered, many times the back and side panels are not, and you could easily add an overflow like these from
Modular Marine to any of those panels, like what
@RocketEngineer mentioned.
My comment is that I personally would redo the silicon seams of this tank. I have for years scraped all the interior silicon out of an old tank, cleaned the glass well with acetone, and reapplied new, aquarium safe silicon. I've done this on over 12 tanks I'd guess, the largest were a 75 and a 125, all standard, rimmed tanks (the 125 I know is still holding water 7 years later, though it's not my tank). This has always worked well for me going back many years now.
However, more recently here on R2R I've been told that doing this in not recommended. Many here say that to reseal a tank you necessarily need to separate the glass panels and remove even the little bit of silicon in between the panels and more or less rebuild the tank from scratch. They say that to leave the old silicon in between the glass in inviting a catastrophe.
Good luck with your new tank!