speculation -
1) hungry (
@DinoMagnet asked if skinnier)
---- wants more food
2) territorial
---- defending from others
--------- conflicting info on 20 long or 30 gallons as
minimum size
--------- 50 liters is only 13.2 gallons (less when rocks, etc added)
keep an eye on your goby. If he does seem to be getting thinner despite target feeding then perhaps look into an autofeeder to drop some pellets during day while you are at work
if it is territorial (not triggered by hunger) then likely there isn't anything you can do about it, but when you have a larger tank then it likely would prefer more space to call its own.
its important to note that even given species generalized preferences, its an individual fish. Just like 10 humans are different from 10 other humans, your fish may be different from other diamond watchman gobies.
Continue to observe and keep us posted. Wishing you and your fish the best!!