On topic...you theoretically should be able to wire those batteries in parallel and double your storage capacity, but you will also increase the available amperage. This may or may not be a problem for your pump. Given the complete lack of safety charge/discharge circuitry in that backup, I wouldn't risk my powerhead (or a fire) by modifying this thing.
Slightly off-topic rant aimed at the industry and not OP (you bought one of the few products available out of best intentions)...
For the price, I was shocked at how little EcoTech put into that battery system!!! If your picture is correct, then there is no charge/discharge control circuit or attempt at a battery tender? This is a $30 battery (retail), a few wires, a plastic box, and a sticker. It cost them probably less than $10 to manufacture and probably another $10 to market and distribute. Maybe EcoTech stickers are worth $180, but it sure won't save my tank when the power goes out.
I have added a photo of the inside of my IceCap battery backup. You can see the circuit that theoretically works as a charge controller for the battery, regulates the output amperage, and auto switches to backup when the power goes out. I expected the EcoTech to be a more sophisticated system that would be better at maintaining the battery or perhaps extending the run-time... I guess not.
For my money, the IceCap is a better built system, but also deficient. A few features that we need are:
- A UPS that is purpose built for 12v and 24v DC aquarium pumps.
-Better battery cells. IME the small cheap Pb AGM style batteries rapidly degrade to the point where it will not supply sufficient voltage to run a powerhead. I just tested mine and it is putting out 8v and needs to be replaced again after 1 year.
- Better battery tending features. A battery tender/trickle charge system is super common for storing automotive batteries. If LiPo bateries are used the system should have smart battery management like most modern phones to avoid overcharge and deep discharge.
- The UPS should have a self test feature to alert you proactively when the cells are degraded and will not power your equipment. If the battery won't deliver ~12v at 1 amp then it won't run my MP10. I shouldn't have to test this monthly.
For $215 for the EcoTech battery (or $195 for IceCap), we ought to be getting a lot more for the money. We need to demand better backup systems. Power outages claim tanks every year driving people out of the hobby. Backup batteries can keep vital equipment running until you can get a generator or bigger battery setup.