I don’t think mine varies much, though I’ve not carefully tracked it. It’s a mid day measurement, but I think I have as much or more photosynthesis at night in my lit refugia.
So you are taking at least one step to keep your pH up, but it's biological instead of chemical.
In addition to kalkwasser, I also run my fuge light at night and I'm pulling outside air through a CO2 scrubber into my skimmer. These are all steps to keep my pH up.
