There are probably 1/2 doz things to consider.
Starting with the effective angle of any reflectors for the t5's.
The height over the tank.
The width of the tank.
The spread from the Viparspectras. How far away from them.Want to eliminate glare or shadows.
Start with how wide is the tank?
Next Vipars like to be high. The lensing is pretty severe so you need it up to get decent f/back spread while the t5's like to be low.
Matter of fact that is one of the main reasons to tilt them in in the first place
You could probably just as easily optimize them by using the distance away from the Viparspectras.
A slight tilt to combat glare .. or you can use them as a shield sort of from the Vipar glare.
Think mounting so as to be slighty below the plain of the Vipars.
"I" don't know anyone who's done serious work on optimizing it. Mostly "it's what it is" or tweak on the fly.
Oh and as much fun as it is you may want to consider using already optimized commercial reflectors.
https://www.coralvue.com/giesemann-high-output-t5-reflectors
At $80 for 4 lenses..I'd consider it reasonable.
Save $12 by using 2 24's per light.. ;) $68
You can probably get the lens angle from Giesemann.
The Aurora design is physicality similar to what you are working with. The leds though probably spread more than the vipars.
https://www.giesemann.de/en/light/hybrid/aurora-hybrid
It would be nice if they told you what they are..
My guess is 90 on the t5's 20 on the leds.
You would have 90(60) on the leds 90 on the t5's
Another EDIT.. The reflectors can be tilted instead of the fixture.