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Thank you so much now I totally understand. I did bit more research because of you chart and I got it and appreciate you input.I have been busy and just got around to analyzing the two ICP results. A group of us did this on a larger scale several years ago, now forgotten. Anyway, the story remains the same, OES tends to become quite variable below 10 ppb and results deviate from MS. In the plot below, the X-axis is micromolar. The relative difference data (Y-axis) is Triton minus Oceamo divided by the average of the two for elements in common. If we were comparing just OES results, the variability would still be apparent starting about 10 ppb or 10 micromolar. The take home message is you need to spend more money for accuracy below 10 ppb. If you are not particularly interested in all the trace elements, save your money and use OES detection.
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10 ppb is not the same as 10 micromolar (µM). The conversion depends on the element’s atomic weight. For example, 10 ppb iodine is only about 0.079 µM, while 10 ppb lithium is about 1.44 µM.
