Running an led fixture at that level for that long shouldn't be a problem for the coral. However, after about 6 to 8 hours the zooxanthellae (algae) inside the coral polyps is NOT doing photosynthesis anymore. It may still be using some of that light energy to build pigments but not making food. Your corals really don't care about sunrise or sunset at all, that's just something we do because it makes us feel good, however it is possible your fish may appreciate it to some very small degree.