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good idea. I'll run the light two hours earlier see how it goes. ThanksI've seen dissolved oxygen levels influence ORP values. Looking at your pH, and the time the lights are coming on, I think you're seeing a normal fluctuation between night/day due to photosynthesis.
You could try turning the lights on a couple of hours earlier - if the trends shift equally, then I'd say that is what is going on....lower CO2 and higher DO once the lights crank up.
Jay