Oxygen issue this morning, looking for causes

not sleeping so i am reporting some ph measurements:

8pm (almost lights out): 8.2
10pm: 8.0
12am: 7.8

I chickened out and placed the airstone back in.

Notes. Measurements using red sea ph test kit. Apparently this is the only kit they have where the colors actually match the card…

There is a safer way to test this: take a half gallon of water out before lights on in the morning, measure the pH, then aerate it for 8 hours and retest.

The drop you saw in four hours does seem to indicate there is a gas exchange issue….
 
6:30am: 7.8 (with airstone)
To me, that indicates the pH would have gone even lower without aeration.

That said, accurate pH measurements are always a challenge.
 
There is a safer way to test this: take a half gallon of water out before lights on in the morning, measure the pH, then aerate it for 8 hours and retest.

The drop you saw in four hours does seem to indicate there is a gas exchange issue….
I did a water change this morning. Got this test setup on half a bucket (~2.5gal). Will report numbers this afternoon.
 
Also, for what its worth here is a pic of the tank. I am fighting some algae but it has not fully taken over. Also you can see the surface agitation in the pic.
IMG_3824.jpeg
 
I did a water change this morning. Got this test setup on half a bucket (~2.5gal). Will report numbers this afternoon.

The water sample needs to be before lights on and before any water change....
 
The water sample needs to be before lights on and before any water change....
Water was removed prior to lights on(beat lights on by 15 minutes!!). Test water is not diluted with new water, came out from the tank and set aside prior to putting “new” water in to replace.
 
Maybe farfetched, but could you have had a power outage for several hours that reversed by morning just around the time you woke up ? maybe the fish recovered coinciding with the time airstone placed
 
The test water is still measuring 8.0 as of right now.

The tank went from 7.8 this morning to 8.2 as of right now.

A rise of 0.4 pH units shows a small amount of CO 2, but not a dangerous amount IMO.
 

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