So you want to run two tanks off one sump essentially, but it sounds like you want them in sort of a series. Main tank draining to this tank and that to the sump? The easiest way would be plumb new tank to sump and either split your return between the two or give it its own return pump. The other way would involve drilling your main tank and making sure the new tank was in a position to receive water via gravity then sending that water to the sump. Much harder way of doing it. If your tank is drilled through the back near the top it may not be that much of an issue but the new tank would need to sit well below that and still be above the sump. Plumb overflow from existing tank to new tank, new tank to sump return water to existing tank. Besides gravity you would need to make sure the new tanks overflow was capable of handling the water coming out of the existing tanks overflow.