If previously happy LPS and zoas are closing then something is definitely off. I would start with nutrients. I think you quoted a surprise 0/0. Are you using Hanna for PO4? Fix PO4 for sure. Let the skimmer drain back into sump. Or cut back refugium hours. Or feed an extra couple times (my favorite). One lever at a time then watch and measure for a week or so before pulling another lever.
Lastly, I don't know the concentration of your 2-part dosing, but sounds like a lot for the amount of stony corals you have. Kinda puzzles me. Maybe my ESV is just more concentrated.
I actually have not ran my skimmer since reading zero, just tested everything (will post a photo). I’m using Hanna for PO4 and alk, Red Sea NO3 pro, salifert for calcium magnesium and to double check alk.
Yeah I really don’t understand the consumption either, I mean I’m getting some corraline growth so there is some uptake. I’m using BRS two part, and just mixed it according to the instructions on the back. I just stopped dosing acro power, because that’s something new within the last month. I lowered my light intensity as well, just because stuff looks so unhappy and losing sps. I don’t think any contaminate has gotten into the water, my RODI is reading zero tds, but will be changing filters this weekend just to be sure. Also just did a water change today, first one in almost a month now maybe.