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I have wanted to do this for a while.. I really haven't heard of any negative effects.. I ran across this vitamin c dosing calculator.. you could try this and read about it here
http://www.humboldtreefclub.com/articles/Vitamin-C-Dosing
I have dosed Vitiman C in the past because I was having some issues with my zoas. Made a world of difference for my tank, don't think it impacted ph to much. But it sure helped my zoas recover.. Here is a link to the thread that i had started about my zoas.