No WC the last 2.5 years - Tank - a little more than 4 years old
Sincerely Lasse
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Krypton!!! LolYou are actually changing more water than I do and some people can go for years without changing water. It is not as important as many people think.
After having said that I still think some water changes should be done.
Carbon and phosguard do not remove everything and I don't even use any of them because they may remove some trace elements that I do not want to remove.
There are many trace elements in sea water that we can't or don't want to test for and it is just easier to change the water.
Sea water has every element on Earth in it including sulphur, gold, Protactinium, Amino Acids, vanadium and we don't have the slightest idea if most of them are needed or not. Even things like Krypton and other elements I can't even spell.
Those trace elements I am sure are slowly removed by your carbon, corals and possibly the fish.
Element mg/kg Cl = 19.00 ‰ mg-atoms/L Cl = 19.00 ‰ Atomic weight (1940) 1/atomic weight Authority Chlorine 18980 548.30 35.457 0.02820 Sodium 10561 470.15 22.997 0.04348 Magnesium 1272 53.57 24.32 0.04112 Sulphur 884 28.24 32.06 0.03119 Calcium 400 10.24 40.08 0.02495 Potassium 380 9.96 39.096 0.02558 Bromine 65 0.83 79.916 0.01251 Carbon 28 2.34 12.01 0.08326 Strontium 13 0.15 87.63 0.01141 Boron 4.6 0.43 10.82 0.09242 Silicon 0.02 –4.0 0.0007 –0.14 28.06 0.03564 Fluorine 1.4 0.07 19.00 0.05263 Nitrogen (comp.) 0.01 –0.7 0.001 –0.05 14.008 0.07139 Aluminum 0.5 0.02 26.97 0.03708 Rubidium 0.2 0.002 85.48 0.01170 Lithium 0.1 0.014 6.940 0.14409 Phosphorus 0.001–0.10 0.00003–0.003 30.98 0.03228 Barium 0.05 0.0004 137.36 0.00728 Iodine 0.05 0.0004 126.92 0.00788 Arsenic 0.01–0.02 0.00015–0.0003 74.91 0.01335 Iron 0.002–0.02 0.00003–0.0003 55.85 0.01791 Manganese 0.001–0.01 0.00002–0.0002 54.93 0.01820 Copper 0.001–0.01 0.00002–0.0002 63.57 0.01573 Zinc 0.005 0.00008 65.38 0.01530 Atkins (1936) Lead 0.004 0.00002 207.21 0.00483 Boury (1938) Selenium 0.004 0.00005 78.96 0.01266 Goldschmidt and Strock (1935)
― 177 ―Cesium0.002 0.00002 132.91 0.00752 Wattenberg (1938) Uranium 0.0015 0.00001 238.07 0.00420 Föyn et al (1939) Molybdenum 0.0005 0.000005 95.95 0.01042 Ernst and Hoermann (1936) Thorium <0.0005 <0.000002 232.12 0.00431 Föyn et al (1939) Cerium 0.0004 0.000003 140.13 0.00714 Goldschmidt (1937) Silver 0.0003 0.000003 107.880 0.00927 Haber (1928) Vanadium 0.0003 0.000006 50.95 0.01963 Ernst and Hoermann (1936) Lanthanum 0.0003 0.000002 138.92 0.00720 Goldschmidt (1937) Yttrium 0.0003 0.000003 88.92 0.01125 Goldschmidt (1937) Nickel 0.0001 0.000002 58.69 0.01704 Ernst and Hoermann (1936) Scandium 0.00004 0.0000009 45.10 0.02217 Goldschmidt (1937) Mercury 0.00003 0.0000001 200.61 0.00498 Goldschmidt (1937) Gold 0.000006 0.00000002 197.2 0.00507 Haber (1928) Radium 0.2 – 3 × 10−10 0.8 – 12 × 10−13 226.05 0.00442 Evans, Kip, and Moberg (1938) Cadmium Fox and Ramage (1931) Chromium Webb (1937) Cobalt Thompson and Robinson (1932) Tin Thompson and Robinson (1932)
― 1
I agree, also unless your using ocean water, the salts your using are fortified with trace. There is no reason to believe that the salt you use for wc are any more element rich then dosing trace using additives. It just seems to be more efficient to dose trace than to attempt at supplementing trace through wc. It’s the efficiency of using a concentrate.You are actually changing more water than I do and some people can go for years without changing water. It is not as important as many people think.
After having said that I still think some water changes should be done.
Carbon and phosguard do not remove everything and I don't even use any of them because they may remove some trace elements that I do not want to remove.
There are many trace elements in sea water that we can't or don't want to test for and it is just easier to change the water.
Sea water has every element on Earth in it including sulphur, gold, Protactinium, Amino Acids, vanadium and we don't have the slightest idea if most of them are needed or not. Even things like Krypton and other elements I can't even spell.
Those trace elements I am sure are slowly removed by your carbon, corals and possibly the fish.
Element mg/kg Cl = 19.00 ‰ mg-atoms/L Cl = 19.00 ‰ Atomic weight (1940) 1/atomic weight Authority Chlorine 18980 548.30 35.457 0.02820 Sodium 10561 470.15 22.997 0.04348 Magnesium 1272 53.57 24.32 0.04112 Sulphur 884 28.24 32.06 0.03119 Calcium 400 10.24 40.08 0.02495 Potassium 380 9.96 39.096 0.02558 Bromine 65 0.83 79.916 0.01251 Carbon 28 2.34 12.01 0.08326 Strontium 13 0.15 87.63 0.01141 Boron 4.6 0.43 10.82 0.09242 Silicon 0.02 –4.0 0.0007 –0.14 28.06 0.03564 Fluorine 1.4 0.07 19.00 0.05263 Nitrogen (comp.) 0.01 –0.7 0.001 –0.05 14.008 0.07139 Aluminum 0.5 0.02 26.97 0.03708 Rubidium 0.2 0.002 85.48 0.01170 Lithium 0.1 0.014 6.940 0.14409 Phosphorus 0.001–0.10 0.00003–0.003 30.98 0.03228 Barium 0.05 0.0004 137.36 0.00728 Iodine 0.05 0.0004 126.92 0.00788 Arsenic 0.01–0.02 0.00015–0.0003 74.91 0.01335 Iron 0.002–0.02 0.00003–0.0003 55.85 0.01791 Manganese 0.001–0.01 0.00002–0.0002 54.93 0.01820 Copper 0.001–0.01 0.00002–0.0002 63.57 0.01573 Zinc 0.005 0.00008 65.38 0.01530 Atkins (1936) Lead 0.004 0.00002 207.21 0.00483 Boury (1938) Selenium 0.004 0.00005 78.96 0.01266 Goldschmidt and Strock (1935)
― 177 ―Cesium0.002 0.00002 132.91 0.00752 Wattenberg (1938) Uranium 0.0015 0.00001 238.07 0.00420 Föyn et al (1939) Molybdenum 0.0005 0.000005 95.95 0.01042 Ernst and Hoermann (1936) Thorium <0.0005 <0.000002 232.12 0.00431 Föyn et al (1939) Cerium 0.0004 0.000003 140.13 0.00714 Goldschmidt (1937) Silver 0.0003 0.000003 107.880 0.00927 Haber (1928) Vanadium 0.0003 0.000006 50.95 0.01963 Ernst and Hoermann (1936) Lanthanum 0.0003 0.000002 138.92 0.00720 Goldschmidt (1937) Yttrium 0.0003 0.000003 88.92 0.01125 Goldschmidt (1937) Nickel 0.0001 0.000002 58.69 0.01704 Ernst and Hoermann (1936) Scandium 0.00004 0.0000009 45.10 0.02217 Goldschmidt (1937) Mercury 0.00003 0.0000001 200.61 0.00498 Goldschmidt (1937) Gold 0.000006 0.00000002 197.2 0.00507 Haber (1928) Radium 0.2 – 3 × 10−10 0.8 – 12 × 10−13 226.05 0.00442 Evans, Kip, and Moberg (1938) Cadmium Fox and Ramage (1931) Chromium Webb (1937) Cobalt Thompson and Robinson (1932) Tin Thompson and Robinson (1932)
― 1
I have said it before and I say it again. Regular WC with artificially saltwater is NOT a safe way to make sure that the level of trace is correct. Some of these traces concentrations are in the gram range per metric ton dry salt. There are no person (or company) that can guarantee an even mix of trace compounds in each batch if it is only needed some grams in one metric ton. There is salts that are based on eveproperated seawater - it could be better but rise other questions. I did the change to no regular WC because of better control of my water quality with help of trace elements and ICP test every 3 month.I agree, also unless your using ocean water, the salts your using are fortified with trace. There is no reason to believe that the salt you use for wc are any more element rich then dosing trace using additives. It just seems to be more efficient to dose trace than to attempt at supplementing trace through wc. It’s the efficiency of using a concentrate.
Krypton!!! Lol
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Summary We have determined the solubility equilibrium concentrations of atmospheric helium, neon, argon, krypton, and xenon in water and seawater over the over a temperature range of approximately freezing point to about 35°C and a salinity range of 0 to roughly 36.7 PSU |
Hey Lasse, do you think ICP is even necessary? It seems to me that ICP is more a failsafe for a catastrophic event then something that would be beneficial as a routine. My logic is that since there is uncertainty to the trace requirements of corals, the information obtained from ICP is too precise and impractical for reef hobby purposes. In other words we don’t know what our target objective is so why are we buying specific data that we don’t have a strategy for nor a practical method to implement. Having said that, I think ICP is a useful tool when the tank is acting unusual despite solid parameters. Seems to me that the practical approach would be to use a general purpose dosing routine like Redsea color program, dose conservatively and test to see what works for you. This way you dose trace like a multivitamin to ensure that your known basis are covered. I know everyone does no WC differently and there are many methods out there, just wanted to see what your reasonings were on ICP.I have said it before and I say it again. Regular WC with artificially saltwater is NOT a safe way to make sure that the level of trace is correct. Some of these traces concentrations are in the gram range per metric ton dry salt. There are no person (or company) that can guarantee an even mix of trace compounds in each batch if it is only needed some grams in one metric ton. There is salts that are based on eveproperated seawater - it could be better but rise other questions. I did the change to no regular WC because of better control of my water quality with help of trace elements and ICP test every 3 month.
Sincerely Lasse
Now that’s a chart!You are actually changing more water than I do and some people can go for years without changing water. It is not as important as many people think.
After having said that I still think some water changes should be done.
Carbon and phosguard do not remove everything and I don't even use any of them because they may remove some trace elements that I do not want to remove.
There are many trace elements in sea water that we can't or don't want to test for and it is just easier to change the water.
Sea water has every element on Earth in it including sulphur, gold, Protactinium, Amino Acids, vanadium and we don't have the slightest idea if most of them are needed or not. Even things like Krypton and other elements I can't even spell.
Those trace elements I am sure are slowly removed by your carbon, corals and possibly the fish.
Element mg/kg Cl = 19.00 ‰ mg-atoms/L Cl = 19.00 ‰ Atomic weight (1940) 1/atomic weight Authority Chlorine 18980 548.30 35.457 0.02820 Sodium 10561 470.15 22.997 0.04348 Magnesium 1272 53.57 24.32 0.04112 Sulphur 884 28.24 32.06 0.03119 Calcium 400 10.24 40.08 0.02495 Potassium 380 9.96 39.096 0.02558 Bromine 65 0.83 79.916 0.01251 Carbon 28 2.34 12.01 0.08326 Strontium 13 0.15 87.63 0.01141 Boron 4.6 0.43 10.82 0.09242 Silicon 0.02 –4.0 0.0007 –0.14 28.06 0.03564 Fluorine 1.4 0.07 19.00 0.05263 Nitrogen (comp.) 0.01 –0.7 0.001 –0.05 14.008 0.07139 Aluminum 0.5 0.02 26.97 0.03708 Rubidium 0.2 0.002 85.48 0.01170 Lithium 0.1 0.014 6.940 0.14409 Phosphorus 0.001–0.10 0.00003–0.003 30.98 0.03228 Barium 0.05 0.0004 137.36 0.00728 Iodine 0.05 0.0004 126.92 0.00788 Arsenic 0.01–0.02 0.00015–0.0003 74.91 0.01335 Iron 0.002–0.02 0.00003–0.0003 55.85 0.01791 Manganese 0.001–0.01 0.00002–0.0002 54.93 0.01820 Copper 0.001–0.01 0.00002–0.0002 63.57 0.01573 Zinc 0.005 0.00008 65.38 0.01530 Atkins (1936) Lead 0.004 0.00002 207.21 0.00483 Boury (1938) Selenium 0.004 0.00005 78.96 0.01266 Goldschmidt and Strock (1935)
― 177 ―Cesium0.002 0.00002 132.91 0.00752 Wattenberg (1938) Uranium 0.0015 0.00001 238.07 0.00420 Föyn et al (1939) Molybdenum 0.0005 0.000005 95.95 0.01042 Ernst and Hoermann (1936) Thorium <0.0005 <0.000002 232.12 0.00431 Föyn et al (1939) Cerium 0.0004 0.000003 140.13 0.00714 Goldschmidt (1937) Silver 0.0003 0.000003 107.880 0.00927 Haber (1928) Vanadium 0.0003 0.000006 50.95 0.01963 Ernst and Hoermann (1936) Lanthanum 0.0003 0.000002 138.92 0.00720 Goldschmidt (1937) Yttrium 0.0003 0.000003 88.92 0.01125 Goldschmidt (1937) Nickel 0.0001 0.000002 58.69 0.01704 Ernst and Hoermann (1936) Scandium 0.00004 0.0000009 45.10 0.02217 Goldschmidt (1937) Mercury 0.00003 0.0000001 200.61 0.00498 Goldschmidt (1937) Gold 0.000006 0.00000002 197.2 0.00507 Haber (1928) Radium 0.2 – 3 × 10−10 0.8 – 12 × 10−13 226.05 0.00442 Evans, Kip, and Moberg (1938) Cadmium Fox and Ramage (1931) Chromium Webb (1937) Cobalt Thompson and Robinson (1932) Tin Thompson and Robinson (1932)
― 1
Now that’s a chart!
Uncle99, the vast majority of tanks on these forums are under 4 or 5 years old and any tank can go for that time frame without doing anything.
People say they have "Great Success" with no water change, no dosing, no nothing and they started their tank last Tuesday.
I would assume, because many tanks can go for years with no water changes that those minor trace elements are utilized so slowly, that the tank can go for years. Eventually, I believe something will suffer. For instance our inverts, especially crustaceans need Iodine and won't live without it.
Our fish, like us need iron and copper. We don't does copper and most of us don't dose iron, but if they run out, the fish will die.
Our tanks get a little copper and iron from our plumbing but not much with RO/Di that we use now. Some of the minerals are also supplied in foods such as clams which are full of minerals.
Potassium, zinc and chromium is used by our bodies and probably fish. Does anyone here dose chromium?
So, if that’s true, are you saying that the minor elements replenish themselves by age?I think a tank of appropriate that has grown from frag to colony size and have enough micro fauna ( pods, liverock, sand etc) can grow into a self sustaining environment without need of water change except for water that has evaporated. ( Eg. look at those enclosed glass ecospheres with a shrimp, seaweed...snail.) but some luck comes to play as well. Reefer luminaries like Sanje has done it. Softy tanks which is less demanding for minerals from water changes , you will have a better chance but hats off to those like Paul who has SPS! Also, even the Jake guy over at reef builder says he feeds his new nano tank fishes only 3 times a week and hasn't done any water changes in several months for the fairly new softie nano tank. Secret is to keep it at a bonsai state without goal of growing the corals and fish super big. I also know a guy with a yellow tang 20 years old is not much bigger than ones you buy at stores... again, he feed his fish substitently.
There are many studies about the uptake of minor elements in Stoney’s. Each one of them clearly indicate what elements have been found in coral skeleton.Re: trace elements.
Those of you claiming the trace element argument please provide me proof and analysis of your favorite salt mix. Salt mixes arent regulated, have no standards, and the term 'trace element" can mean whatever the manufacturer wants.
The main reason for water changes is to export nutrients and keep some tanks from getting into triple digit nitrates. I personally think it's a waste of time and wasteful in terms of resources.
Can you show me a pic of your tank which has not had a water change in 7 years?I do not know where the elements would come from...from the rocks;algae;Fish / pod poop? I will leave that to the marine biologist. I have an 10 gallon apitisa tank ( was going to grow berghia) that is probably 7 years old. Never changed water or any except for evaporated water and a light and powerhead. Apitsa doing just fine as is.