Wierd rusty stain coral glue

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Kingsley_Reef

Kingsley_Reef

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Has anyone seen this? I glued this small frag to the plug about a month ago it broke off today and found this strange stain where the glue was applied
 
Reef Pro Corals
I cut frags off the plugs (pop them off when I can) and these orange spots have been seen occasionally, no explaination? I assumed it was possibly a microbe, a sponge, a rust spot from chemical reactions?
 

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