You could but you would really want to be careful with the vinegar. You would be essentially carbon dosing and risk dropping your nutrients too low or askew.Here is something google turned up. Maybe add an 1ML of vinegar?
Step 3: Add Organic Acid Like White Vinegar
Adding a small dose of white vinegar can be the game-changer when it comes to lowering the alkalinity in the reef tank. It will help to reduce the alkalinity level almost immediately. However, as it also lowers the pH level, you should not use any organic acid like vinegar frequently.
If the pH level drops significantly due to the use of organic acid, here’s what you should do to restore the pH:
- Stir the surface of the tank water. When you agitate the water, the gas exchange will improve in the water. As a result, the oxygenation of the reef tank will increase the pH level will be back to normal again.
- Move the powerheads and return pump outlets towards the water surface.