It’s a 0,6% pharma grade solution. I even tried to “test” the ammonia solution itself but the vial is still yellow (0 ppm).
Which made me think that if the test is nh4 only, would it not react to ammonium hydroxide?
No, that last sentence is not correct. Any ammonia test can detect that ammonia.
I would not try to test the solution itself, since that may not work. If you take a liter of tank water, add enough of that solution to attain 4 ppm, it should work. If it does not, the solution is not what it claims, or the kit is not working.
How did you determine how much to dose?