They're actually relatively easy to keep in a pair or trio so long as you start with juveniles or females. I had 3 in my old 380 gallon. Bought 2 adult females and paired them up without issue, and 1 small juvenile I added to the pair without issue. They are relatively easy to sex by the size of their gill spike, as are most angelfish. All of them start female and the largest most dominant turns male. Looking at a 4" female and a 4" male side by side, the male's gill spine will be roughly 2x the size.
If you're adding one in with your established fish, my suggestion would be to get the smallest one you can find. Babies are more likely to be accepted.