Introduction:
Many reef tanks have an incredible nitrate demand, and despite the additional fish and coral food, still struggle to make an impact on the nitrate level. This can subject corals, anemones, coralline, macro/microalgae, and clams to nutrient starvation. Any photosynthetic organism requires an external nitrogen source because they cannot synthesize it on their own. While using a
DIY nitrate dosing recipe is a fine plan to increase nitrate, corals and photosynthetic organisms prefer and will readily assimilate ammonia. In order for an organism to utilize nitrate, they must first internally convert it into ammonia; this takes more work and is less bioavailable. When given the choice, these organisms will choose ammonia over nitrate.
Why dose ammonia and what does it do?
Dosing ammonia can accomplish two goals: it increases nitrogen availability, and it can also be used as an indirect nitrate additive. Photosynthetic creatures can still use and benefit from nitrate, and having detectable levels is important to ensure nitrogen is constantly available. Nitrifying bacteria will convert excess ammonia into nitrate. While there is little risk of proper ammonia dosing to accumulate in cycled reef tanks, it also means ammonia will always be in short supply. For this reason, a detectable level of nitrate is recommended.
Ammonium chloride or ammonia bicarbonate?
Ammonium chloride and ammonium bicarbonate are the two common ammonium compounds used in reefkeeping. I prefer ammonium bicarbonate because it has no effect on the alkalinity of the aquarium, whereas ammonium chloride steadily depletes it: every 50 ppm of nitrate equivalents added through ammonium chloride will decrease the alkalinity by 2.3 dKH. It has an acidifying effect. Both are readily available online. It's highly recommended and inexpensive to source food-grade and high purity sources.
Ammonia Recipes:
The original recipes were taken from the
DIY ammonia dosing for low nitrate systems thread by
@Randy Holmes-Farley. I've only conveniently organized the chart and dosing regimen.
Ammonium bicarbonate: most ideal for alkalinity stability. However, it is prone to evaporation and losing potency from air exposure. Keep the solution as tightly sealed as possible, away from chronic air exposure.
Recipe:
20 g ammonium bicarbonate in 1 L of freshwater.
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Ammonium chloride: While the solution is more shelf stable, it will steadily decrease the alkalinity over time, so additional alkalinity compensation may be warranted in tanks receiving substantial ammonium chloride dosing.
Recipe:
13.5 g ammonium chloride in 1 L of freshwater
Both of these solutions have the same concentration: 4300 mg/L (4.3 mg/mL) ammonia, equivalent to 15,700 mg/l nitrate. 2.3 mL of this solution added to 100 L raises ammonia by 0.10 ppm (nitrate equivalent to 0.36 ppm).
Utilice pruebas de nitratos para guiar la dosis.
Se recomienda utilizar los niveles de nitrato como indicador para ajustar la dosificación de amoníaco, ya que la medición directa del amoníaco no es muy precisa para alcanzar los niveles bajos y seguros que buscamos.
1. Si el nitrato está disminuyendo por debajo de su objetivo ideal, hay escasez de nitrógeno (déficit) y se justifica una mayor dosificación de amonio.
2. Si el nitrato se mantiene estable en torno a su objetivo ideal, la dosis está manteniendo la demanda de nitrógeno, que es el objetivo final.
3. Si el nivel de nitrato aumenta por encima del objetivo, hay un excedente y la dosis debe reducirse o suspenderse.
Saber cómo avanzar con el gráfico:
Comience la gráfica desde la primera semana y determine si es necesario aumentar la dosis al final de la semana. Si el nitrato es indetectable y no ha aumentado en 3 o 4 días después de la administración de la dosis, pase a la semana siguiente.
Consejo profesional:
El amonio se puede mezclar con nitrato e incluso con fosfato en la misma solución. No existen interacciones entre ellos.
¿Por qué estamos dosificando amonio en lugar de amoníaco propiamente dicho?
No podemos dosificar fácilmente amoníaco puro, ya que se presenta en estado gaseoso a temperatura y presión ambiente normales. El amonio es un sustituto adecuado porque parte de él se convierte naturalmente en amoníaco en el agua de mar según el pH, de forma similar a como las fuentes de alcalinidad de bicarbonato y carbonato varían entre sí a pesar de dosificar solo una de ellas.