DT and sump water level (not the return area) is a function of weir height, sump baffle height and to a lesser extent pump flow rate. Water volume can have an effect but you would have to add quite a lot extra...
This is generally fixed although some RedSea sumps have an adjustable baffle to adjust the level in one section.
Your sump has had the socks removed so the whole front area is the same (it would normally be higher by the drains).
The baffle behind your reefmat will set this height but may not be adjustable.
You want the level lower (seperated) in the return area as this works better for the ATO. Evaporation will only affect the return area where the ATO sensor/float is and using this smaller volume area means smaller losses are captured quickly rather than waiting for a large volume of water to register a drop in level.
When I carry out water changes I will typically do it in multiples of 25 litre barrels. That is, I either do two or four barrels which is either 50 or 100 litres.
I will heat the water in a separate container then use the empty barrels to gauge how much I have drained. If I'm heating two barrels worth (50 litres) then I drain my DT into the two empty barrels. This way water out equals water in although I typically drain a little bit less to allow for skimmer losses. I do check salinity isn't drifting.
The water level in the system will always settle at the ATO sensor so in my experience it is best to gauge the water level there with the pump running. You can make marks or take measurements anywhere as long as you are consistent but with the pump running the return area and ATO sensor height is the most accurate.
I am happy to do like for like charges to maintain this and only ever check the the water looks about right in the return area or maybe a touch high. If you cannot accurately carry out like for like changes then make a mark in the return chamber and confirm with the pump running.
Over or under filling will only affect the return area unless you are really overdoing it. The rest of the system should set its own height once running. To that end, you won't be able to set the water height for the skimmer by adding water as it is set in that chamber by the baffles. If the skimmer height needs adjustment it can be raised on a platform. FYI, I've raised mine 4 inches to stop it flowing wet foam.