@Brad Coughlan I have used kalkwasser on many tanks, including my current nano that is just a little bigger than yours. I have mixed kalk into top off on larger systems. On smaller systems I use a dosing pump. You’ve gotten good advice above.
Regarding the irrational fear of a dosing pump getting stuck on, I have the same fear, though I have never had it happen. In the past, I would use a float switch to shut down all dosers if the water level got too high, the same way an ATO works. I never once triggered that float switch in many years. On my current set up, I didn’t have room for this float switch so I just rely on my programming timer to turn it off. So far so good. The idea of starting with a smaller volume in the dosing container is a good one.
In your current system, 60ml of saturated kalkwasser will dose about 0.1 dKH. You can start with a small dosing volume, measuring alkalinity and watch the trend. Kalk works well in low demand systems because it takes a large volume to add a large amount of alkalinity.