Ozone and organic phosphates

cvicente

Active Member
Review score
+0 /0 /-0
View Badges
Joined
Feb 25, 2014
Messages
131
Reaction score
101
Review score
+0 /0 /-0
Location
Puerto Rico
Taken from Randy Holmes Farley article "Phosphates and the Reef Aquarium"

"These bonds are stable for some period of time in water, but eventually break down to release inorganic orthophosphate from the molecule's organic part, a process that can be speed up through the action of enzymes in a reef aquarium. Many of these organic phosphate compounds will be readily removed from an aquarium by skimming. Export of organic phosphates is likely the major way that skimming can reduce inorganic orthophosphate levels in an aquarium. Orthophosphate ions are not significantly removed via skimming (because they do not adsorb onto an air/water interface), but organic phosphates can be removed before they are converted into inorganic orthophosphate."

My question is, If ozone is injected through the skimmer, will ozone break down organic phosphates into orthophosphates, thus reducing the effectiveness of the skimmer as a mean of phosphate export mechanism ?
 
Never Wash Another Nasty Filter Sock Again!

BanjoBandito

Valuable Member
Review score
+0 /0 /-0
View Badges
Joined
Jul 24, 2018
Messages
2,301
Reaction score
2,912
Review score
+0 /0 /-0
Location
Butler County, PA
Taken from Randy Holmes Farley article "Phosphates and the Reef Aquarium"

"These bonds are stable for some period of time in water, but eventually break down to release inorganic orthophosphate from the molecule's organic part, a process that can be speed up through the action of enzymes in a reef aquarium. Many of these organic phosphate compounds will be readily removed from an aquarium by skimming. Export of organic phosphates is likely the major way that skimming can reduce inorganic orthophosphate levels in an aquarium. Orthophosphate ions are not significantly removed via skimming (because they do not adsorb onto an air/water interface), but organic phosphates can be removed before they are converted into inorganic orthophosphate."

My question is, If ozone is injected through the skimmer, will ozone break down organic phosphates into orthophosphates, thus reducing the effectiveness of the skimmer as a mean of phosphate export mechanism ?
The only thing I can tell you is anecdotally when running ozone it always decreases the foam production within skimmer chamber and I need to up the air intake for the skimmer itself to stay "foamy".
 

Randy Holmes-Farley

Reef Chemist
Review score
+0 /0 /-0
View Badges
Joined
Sep 5, 2014
Messages
54,550
Reaction score
47,361
Review score
+0 /0 /-0
Location
Arlington, Massachusetts, United States
Ozone is not especially prone to break the P-O-C binding that holds the phosphate to the organics, but it can convert some organics into ones more readily metabolized.
 
World Wide Corals

Let’s talk about stuffing: How full is your tank?

  • My tank is overcrowded.

    Votes: 73 14.1%
  • My tank is nearly full/full but not overcrowded.

    Votes: 174 33.5%
  • My tank is just getting started and growing.

    Votes: 240 46.2%
  • I take a minimalist approach with my tank.

    Votes: 32 6.2%
Top