Ozone and organic phosphates

cvicente

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Taken from Randy Holmes Farley article "Phosphates and the Reef Aquarium"

"These bonds are stable for some period of time in water, but eventually break down to release inorganic orthophosphate from the molecule's organic part, a process that can be speed up through the action of enzymes in a reef aquarium. Many of these organic phosphate compounds will be readily removed from an aquarium by skimming. Export of organic phosphates is likely the major way that skimming can reduce inorganic orthophosphate levels in an aquarium. Orthophosphate ions are not significantly removed via skimming (because they do not adsorb onto an air/water interface), but organic phosphates can be removed before they are converted into inorganic orthophosphate."

My question is, If ozone is injected through the skimmer, will ozone break down organic phosphates into orthophosphates, thus reducing the effectiveness of the skimmer as a mean of phosphate export mechanism ?
 

BanjoBandito

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Taken from Randy Holmes Farley article "Phosphates and the Reef Aquarium"

"These bonds are stable for some period of time in water, but eventually break down to release inorganic orthophosphate from the molecule's organic part, a process that can be speed up through the action of enzymes in a reef aquarium. Many of these organic phosphate compounds will be readily removed from an aquarium by skimming. Export of organic phosphates is likely the major way that skimming can reduce inorganic orthophosphate levels in an aquarium. Orthophosphate ions are not significantly removed via skimming (because they do not adsorb onto an air/water interface), but organic phosphates can be removed before they are converted into inorganic orthophosphate."

My question is, If ozone is injected through the skimmer, will ozone break down organic phosphates into orthophosphates, thus reducing the effectiveness of the skimmer as a mean of phosphate export mechanism ?
The only thing I can tell you is anecdotally when running ozone it always decreases the foam production within skimmer chamber and I need to up the air intake for the skimmer itself to stay "foamy".
 

Randy Holmes-Farley

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Ozone is not especially prone to break the P-O-C binding that holds the phosphate to the organics, but it can convert some organics into ones more readily metabolized.
 

IconCorals

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Hi @Randy Holmes-Farley

Sorry to resurrect a old thread, above you mentioned the process of removing Organic phosphate can be speed up by Enzymes, can I ask what Enzymes exactly?

My tank a year old from dry ceramic reads 0.04 on a Elos high range test kit but when sending a ICP comes back as 0.20 so I'm presuming I have a chunk of organic phosphates, too note my phosphorus also reads high on ICP too

Thanks

All the best

J
 

Randy Holmes-Farley

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Hi @Randy Holmes-Farley

Sorry to resurrect a old thread, above you mentioned the process of removing Organic phosphate can be speed up by Enzymes, can I ask what Enzymes exactly?

My tank a year old from dry ceramic reads 0.04 on a Elos high range test kit but when sending a ICP comes back as 0.20 so I'm presuming I have a chunk of organic phosphates, too note my phosphorus also reads high on ICP too

Thanks

All the best

J

As a rule they would be called phosphatases, but there are many that degrade slightly different organic phosphates. Alkaline phosphatase is a common one.
 

IconCorals

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As a rule they would be called phosphatases, but there are many that degrade slightly different organic phosphates. Alkaline phosphatase is a common one.
Thank you for the clarification, can I ask if you had high organic phosphates how you would go above removing them?

Thanks J
 

Randy Holmes-Farley

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Thank you for the clarification, can I ask if you had high organic phosphates how you would go above removing them?

Thanks J

I’d be skeptical that you do, but if you do I see no reason to lower it.

Phosphate can change during transit.
 

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