It's true that a lot of this information is anecdotal, but with sea stars that eat things which aren't microscopically small (like the biofilms preferred by Fromia and Linckia stars), what they eat is frequently reported by divers in the area (in my experience, these reports from the wild are more likely to be helpful with figuring out the natural diet of the stars than reports from the aquarium hobby/industry, because - as you mentioned - many stars will stray from their natural diet in aquarium settings), and may be readily apparent (sea stars tend to leave a bit of a trail of destruction in their grazing area).
To clarify here, they are completely different species from separate genera - they do look somewhat similar, but they are quite different (though Tosia australis has sometimes been considered a Pentagonaster sp. in the past, it is considered a Tosia sp. today). As was mentioned, the term "Biscuit Star" refers to a wide number of species, some of which may be herbivorous, some of which may be carnivorous, and some of which may be omnivorous. For Pentagonaster duebeni, by all accounts that I can find, they are obligatorily carnivorous. For T. australis, however, they do seem to be omnivores.