From what I understand is that the trophont attaches to the fish for 4-10 days before it drops off into the substrate to reproduce.
Once it enters the theront stage to seek out fish to attach to, this is where copper comes in, as it prevents it from attaching in the first place. This leads to it starving out within 48h.
Going by this logic, if I remove the fish after all trophonts have dropped off, and do not transfer anything else with it, it shouldn't make it into the observation tank.
I guess my question is: in which case would the 14d copper plus transfer method fail? Is it possible the trophont stage may last longer than 14 days? Or could there be copper resistant strains that are capable of attaching to the fish even in fully therapeutic copper levels?
I get what you (and Humblefish) are saying, and I am far, far from an expert. The method you're describing does make sense on paper, but given that guys like Jay H. (works professionally for large public aquaria) suggest a full 30 days, I'm thinking there must be some risk with just a 14 day QT.
To answer your last question, nothing is 100%, even Humble said so at the bottom of the article. There's typically at least a non-zero chance something could get by any QT protocol.