I recently had a similar situation where the sanity levels in our office tank would slowly creep up over the course of a week or two, despite proper topping off with an automated ATO.
It took a while but I finally discovered the source of the issue. It ended up being a slowly failing DC pump power supply. It started providing less and less power to the pump and thus slowed the pump down. As it got slower, the water level in the sump return chamber would not account for the total evaporation, and as a result, the ATO would add less an less water, causing the salinity to slowly increase.
I don't know if you have a DC pump, but if you do, check it and see if there's a way you can verify the amount of flow it is producing. If it's not delivering enough flow, you may need to clean the pump and or you may have a power supply beginning to fail.