Seeking Chemistry understanding

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Rolliad

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I'm sure this is somewhere else, but I'm just recovering from Norovirus, so please bear with me.

My understanding of Alk and Ca is that they have a bit of an inverse relationship - the higher the Alk, the lower the Ca...etc.

The last few weeks, my Alk has creeped up and up and up, for no reason that I can identify. The only thing I've dosed the last 3 weeks is PhosBan - L, which says that it would actually decrease Alk, not increase it. However, my Alk has gone from 8.9 to 11.2 over the course of the last 3 weeks. My normal water change of 10% reduces it for a bit and then it creeps back up again over the course of the week.

Becoming a bit concerned that I have a Ca problem, I've tested my Ca for the last week...and my Ca is also slowly creeping up. This makes no sense to me based on what I know of how this works.

Here are my tank parameters as of this morning:

Temp: 79.1
Salinity: 1.025
pH: 8.35
Nitrates: 35.4
Phosphates: 0.15
Alk: 10.8
Ca: 480
Mag: 1440

I have a bunch of SPS and a few LPS and a couple of leathers. Everything looks fine.

I'm just trying to capture understanding on if I have a problem in the making or no?
 
Not sure about the inverse relationship of Alk/ Calcium.

If Alk is going up and Calc is going up I would reduce any 2/3 part/ AFR etc… dosing.

Next I would check salinity to make sure it has not crept up…
Alk and Calcium do not tend to increase unless they are added or salinity changed.

Good luck,
 
Alk and calcium are not really inverse. That's an oversimplification to the point of inaccuracy. Both can be high or both low.

Are you dosing anything?
 
I've triple checked my salinity and it's 1.025 on all testers.

I'm not dosing anything except for PhosBan - L to bring my phosphates down.
 
How do you replace evaporated water?
RODI with ATO pump controlled by Hydros controller.

I used to dose Kalk, but stopped about a month ago to make sure I get everything dialed in prior to further utilization.
 

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