Ammonium dosing is a bit overrated

NautiTang

Well-Known Member
View Badges
Joined
Mar 30, 2020
Messages
841
Reaction score
2,835
Location
Cheyenne, Wy
Rating - 0%
0   0   0
The best way to cycle a tank is by peeing in it! 🤪
Thats how I started cooking my rock in the 100g stock tank about 8 months ago before dosing ammonia simi-inconsistently thereafter 🤣. I didn't have the ammonia yet but had the rock, it how my uncle taught me to cycle tanks when i was a kid in the 90s.
 

Fish Styx

In Cod We Crust
View Badges
Joined
May 10, 2020
Messages
15,570
Reaction score
90,014
Location
Washington, DC Metro
Rating - 100%
1   0   0
I’m just waiting until I read that someone has started “dosing” their tank with pee every morning because it provides all of the nutrients a healthy reef tank needs.

Nitrate (via urea breakdown), ammonium, potassium, sulfate, calcium, magnesium, iodine, iron, manganese, molybdenum, zinc, selenium…

Trace elements. All natural. No additives. Organically filtered. Free. What’s not to like? Just stay away from asparagus.
This is how we kick started our cycles back in the day.
 

Randy Holmes-Farley

Reef Chemist
View Badges
Joined
Sep 5, 2014
Messages
89,269
Reaction score
92,323
Location
Massachusetts, United States
Rating - 0%
0   0   0
The second part of my question covers this, doesn’t it? (Or at least replies elsewhere).

If there was a magic tester that tests every second instantaneously what’s in the tank, having NO3 maintain 0.1ppm and never go below 0.1ppm implies corals would be getting all the N they need, no?

If you knew the levels of all N sources corals use, and knew those levels were adequate without nitrate, then there would be no need for any nitrate.

Reality is we cannot measure ammonia, and cannot even hope to quantify the utility of all the different dissolved and particulate organics.

So the answer is yes, but it’s impossible to do.
 

Randy Holmes-Farley

Reef Chemist
View Badges
Joined
Sep 5, 2014
Messages
89,269
Reaction score
92,323
Location
Massachusetts, United States
Rating - 0%
0   0   0
Let me also clarify something that might be confusing. Everything a cell (or coral) takes in, becomes harder to do so as the concentration declines. Thus, a coral may have a much easier time getting all the N it needs at a fixed 5 ppm nitrate than at a fixed 0.1 ppm nitrate.

Here’s an analogy that is actually pretty representative of the situation.

Imagine you are in a boat fishing for your family’s dinner. If there are many fish in the water, you might be able to get all you need with a single fishing pole.

But if the number of fish is very low, one pole may get you little or no fish.

Breaking out more and more fishing poles, covering all around the boat may get you what you need.

With even fewer fish around, but still some, even lots of poles may not be enough.
 

rishma

2500 Club Member
View Badges
Joined
Nov 15, 2009
Messages
2,757
Reaction score
2,500
Rating - 0%
0   0   0
Let me also clarify something that might be confusing. Everything a cell (or coral) takes in, becomes harder to do so as the concentration declines. Thus, a coral may have a much easier time getting all the N it needs at a fixed 5 ppm nitrate than at a fixed 0.1 ppm nitrate.

Here’s an analogy that is actually pretty representative of the situation.

Imagine you are in a boat fishing for your family’s dinner. If there are many fish in the water, you might be able to get all you need with a single fishing pole.

But if the number of fish is very low, one pole may get you little or no fish.

Breaking out more and more fishing poles, covering all around the boat may get you what you need.

With even fewer fish around, but still some, even lots of poles may not be enough.
I now know what argument to use next time I try to debate with you about higher phosphate correlating more algae problems 😉
 
OP
OP
Miami Reef

Miami Reef

Reef Chem Enthusiast
View Badges
Joined
Sep 8, 2017
Messages
17,255
Reaction score
29,618
Location
Miami
Rating - 0%
0   0   0
I now know what argument to use next time I try to debate with you about higher phosphate correlating more algae problems 😉
I actually agree with this. I know there’s at least 1 study showing how phosphate at 0.5 ppm grew a coral better than 0.2 and 0.09 ppm

If phosphate isn’t limiting at 0.09 ppm, why would increasing it further increase coral growth?
 
Last edited:

Troylee

all about the diy!!!!!
View Badges
Joined
Jan 15, 2010
Messages
22,206
Reaction score
23,366
Location
Vegas baby!!!!
Rating - 0%
0   0   0
I actually agree with this. I know there’s at least 1 study showing how phosphate at 0.5 ppm grew a coral better than 0.2 and 0.09 ppm

If phosphate isn’t limiting at 0.09 ppm, why would increasing it further increase coral growth?
Because you only know what you’ve read! You’re a newb! Ask @Hans-Werner or @Lou Ekus haha!
 

rishma

2500 Club Member
View Badges
Joined
Nov 15, 2009
Messages
2,757
Reaction score
2,500
Rating - 0%
0   0   0
I actually agree with this. I know there’s at least 1 study showing how phosphate at 0.5 ppm grew a coral better than 0.2 and 0.09 ppm

If phosphate isn’t limiting at 0.09 ppm, why would increasing it further increase coral growth?
Because you only know what you’ve read! You’re a newb! Ask @Hans-Werner or @Lou Ekus haha!
Pots and kettles and all that
 

Randy Holmes-Farley

Reef Chemist
View Badges
Joined
Sep 5, 2014
Messages
89,269
Reaction score
92,323
Location
Massachusetts, United States
Rating - 0%
0   0   0
I now know what argument to use next time I try to debate with you about higher phosphate correlating more algae problems 😉

That would be a rationale, but at least for phytoplankton, studies show that above 0.03 ppm or so, phosphate is not limiting to their growth, something else does. :)
 

rishma

2500 Club Member
View Badges
Joined
Nov 15, 2009
Messages
2,757
Reaction score
2,500
Rating - 0%
0   0   0
I now know what argument to use next time I try to debate with you about higher phosphate correlating more algae problems 😉

That would be a rationale, but at least for phytoplankton, studies show that above 0.03 ppm or so, phosphate is not limiting to their growth, something else does. :)
So your saying there’s a chance…
 

Randy Holmes-Farley

Reef Chemist
View Badges
Joined
Sep 5, 2014
Messages
89,269
Reaction score
92,323
Location
Massachusetts, United States
Rating - 0%
0   0   0
So your saying there’s a chance…

Yes. Something is going to limit algae growth, whether a chemical or light or space competition, or something else, but if a tank has high levels of all of those things, the level where phosphate is the limiting factor will rise.

Do I think typical reef tank algae grow faster in a reef tank at 1 ppm than at 0.5 ppm phosphate? I expect not. That is so far above where they have evolved to get phosphate, and where they have been seen to thrive, that I wouldn’t expect it to be limiting.

If one looks at the effect of concentration on transport uptake ability, such as a phosphate uptake transporter, the curve typically follows something called Michaelis-Mention kinetics, and looks like this, where uptake rises as the concentration rises, and then levels off as the concentration continues to rise. The relative boost to uptake diminishes as concentration gets a lot higher than where the transporter normally shows decent activity. It never gets above 100 in the graph, no matter how high the phosphate gets.


1755006523775.png
 
OP
OP
Miami Reef

Miami Reef

Reef Chem Enthusiast
View Badges
Joined
Sep 8, 2017
Messages
17,255
Reaction score
29,618
Location
Miami
Rating - 0%
0   0   0
Yes. Something is going to limit algae growth, whether a chemical or light or space competition, or something else, but if a tank has high levels of all of those things, the level where phosphate is the limiting factor will rise.

Do I think typical reef tank algae grow faster in a reef tank at 1 ppm than at 0.5 ppm phosphate? I expect not. That is so far above where they have evolved to get phosphate, and where they have been seen to thrive, that I wouldn’t expect it to be limiting.

If one looks at the effect of concentration on transport uptake ability, such as a phosphate uptake transporter, the curve typically follows something called Michaelis-Mention kinetics, and looks like this, where uptake rises as the concentration rises, and then levels off as the concentration continues to rise. The relative boost to uptake diminishes as concentration gets a lot higher than where the transporter normally shows decent activity. It never gets above 100 in the graph, no matter how high the phosphate gets.


1755006523775.png
I’ve always wondered if there is a point of diminishing returns. I’m thinking something akin to copper; it’s a needed trace element, but too much is toxic. Another example is par. I wonder if there’s a level of phosphate and nitrate where increasing it doesn’t just stop the benefits but also decreases and slows growth.
 

Randy Holmes-Farley

Reef Chemist
View Badges
Joined
Sep 5, 2014
Messages
89,269
Reaction score
92,323
Location
Massachusetts, United States
Rating - 0%
0   0   0
I’ve always wondered if there is a point of diminishing returns. I’m thinking something akin to copper; it’s a needed trace element, but too much is toxic. Another example is par. I wonder if there’s a level of phosphate and nitrate where increasing it doesn’t just stop the benefits but also decreases and slows growth.

There certainly will be some level at which phosphate starts causing problems,,even if that is limited to things like precipitating iron and limiting it (the DSR method precipitated phosphate with added soluble iron). Since it coats calcium carbonate surfaces, that is certainly a mechanism to inhibit calcification if it makes it to the location where skeletal formation is taking place.

Not sure what levels cause which problems, however.
 

Hans-Werner

Valuable Member
View Badges
Joined
Aug 24, 2016
Messages
1,994
Reaction score
3,042
Rating - 0%
0   0   0
I stepped in because Troylee mentioned me, thank you @Troylee !

I am not sure whether I already have understood the question, I didn't read the complete thread.

I’ve always wondered if there is a point of diminishing returns. I’m thinking something akin to copper; it’s a needed trace element, but too much is toxic. Another example is par. I wonder if there’s a level of phosphate and nitrate where increasing it doesn’t just stop the benefits but also decreases and slows growth.

There certainly will be some level at which phosphate starts causing problems,,even if that is limited to things like precipitating iron and limiting it (the DSR method precipitated phosphate with added soluble iron). Since it coats calcium carbonate surfaces, that is certainly a mechanism to inhibit calcification if it makes it to the location where skeletal formation is taking place.

Not sure what levels cause which problems, however.
In my opinion this goes into the right direction. I think higher iron concentration even can inhibit coral growth and support algal growth. This could be a kind of tipping point switching conditions from beneficial for corals to beneficial for algae and vice versa. Any measure that limits iron to a low concentration could be helpful. This could be high phosphate or nitrate concentrations and maybe even manganese which may coprecipitate iron.

This is just a theory from my own observations but maybe something to watch and think about.
 
OP
OP
Miami Reef

Miami Reef

Reef Chem Enthusiast
View Badges
Joined
Sep 8, 2017
Messages
17,255
Reaction score
29,618
Location
Miami
Rating - 0%
0   0   0
Hmm. I’ve been playing with iron dosing after struggling to grow algae in my turf scrubber. I read it can be limiting to zooxanthellae, too, so I was curious if I’d see a growth response to corals by dosing it.
 

Troylee

all about the diy!!!!!
View Badges
Joined
Jan 15, 2010
Messages
22,206
Reaction score
23,366
Location
Vegas baby!!!!
Rating - 0%
0   0   0
Hey Lee! Saw your pic of the month on Facebook with your torch. Great pic you newb
Haha! Thanks. Yeah that was cool… made the cover for a day or something…
 

Troylee

all about the diy!!!!!
View Badges
Joined
Jan 15, 2010
Messages
22,206
Reaction score
23,366
Location
Vegas baby!!!!
Rating - 0%
0   0   0
I heard through the grapevine that you are switching to Moonshine?

Edit: Teasing - you newb!
Nah that stuff gives me a nasty hangover lol..
 

TOP 10 Trending Threads

WHAT AMOUNT OF LIVE ROCK AND SAND SHOULD BE PRIORITIZED FOR OPTIMAL BIODIVERSITY/FILTRATION?

  • 100% live rock + bagged sand

    Votes: 38 26.6%
  • 100% dry rock + 100% live sand

    Votes: 48 33.6%
  • 50/50 live/dry rock, 50/50 live/bagged sand

    Votes: 32 22.4%
  • 75% live rock, 25% live sand

    Votes: 15 10.5%
  • 25% live rock, 75% live sand

    Votes: 10 7.0%
Back
Top