First off, congrats, sounds like you've jumped in with both feet and got some nice equipment. Better to buy once and cry once.
So now you know why your tank was trending towards 6 dkh, it's because that's what your mix water is at. Here's what I'd suggest. You've obviously got a nice system and equipment, take it one step further and make your own water. All you need is a brute can, an RO system, and some salt. You'll save money and time, and know your params. If you want to start small, the RO Buddie on
amazon is a good kit, otherwise go with the
BRS systems.
^Optional, but might fix your problem altogether. Until you know you're putting the right water in during water changes, you'll constantly be playing the test/dose catch up game.
FWIW, the params in your LFS water actually match a fish-only system. Maybe that's why they mix to those params. Def not what you want if you keep corals.
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To get your tank back on track, first get your salinity stable and keep it there. I believe the Milwaukee will auto-adjust for temperature. That's good.
Next, check your mag. If it's above 1290-1300, it's prob not your prob. But raise it to 1320 anyway, it'll help stabilize your alk.
Next, you need to realize that there's an inverse relationship between alk and ca. If you goes up, the other goes down. So your goal is to get to the point where you don't need to dose only one element, but both in equal measure. To get to this point, yes you may need to dose elements one at a time. But also getting your water change water at the right params, so you can change more frequently to get back on track, is going to be critical.