My recommendation is to dose AFR in an amount sufficient to maintain your target alk. If you choose to measure calcium (I do not since I think it unnecessary when dosing just AFR) then IF it gets above 550 ppm and is still rising, then I’d back off on the AFR dose and use baking soda or other alk additive for a portion of the alk demand. That will stop the calcium rise and/or allow it to fall.
I don’t think the calcium rise is going to be excessive in most tanks getting regular water changes with a normal or low level of calcium. The water change will keep it under control. Folks see it rising through the 400s and worry, but needlessly so, IMO.
A tank dosing a huge amount of AFR or a tank with no water changes will be more likely to show an issue and need to dose a small part of the alk by normal alk additive.
I did this for 20 years in my old tank dosing kalk at 2 dKH per day. It has an identical alk to calcium ratio as AFR, and doing 1% daily water change with IO, calcium stabilized at 450 ppm.
Can it work to set the dose on calcium? Yes. But it is more prone to excessive jiggering of the dose as the calcium test result wobbles around due to salinity changes and mostly, test inaccuracy. That then may cause a big swing in alk, when it was just a small change in calcium. A correction of a 20 ppm change/error in calcium results in a big 2.8 dKH swing in alk.