Did you test the DI water straight from the RO/DI output or from the storage container? If its from the unit then thats probably not good, if its from the container it could just be dust or residual salt.
What is the TDS of the RO only water before it gets to the DI?
If the RO is lower than the 19 then that means you are releasing weakly ionized substances from the spent DI resin and it could be all nitrates, phosphates and silicates which are all weakly ionized substances.
If the RO only is about equal to or greater than the 19 then its possible the DI is doing a little bit of work but is near exhaustion and will soon begin sloughing off and releasing everything it has captured over time.
DI must also be stored wet and cool or it loses its electrical charge, if you are not using the RO/DI for an extended period remove the membrane and DI cartridges and stick them in the refrigerator in a zip loc bag with some DI water in it so they stay fresher. Even then DI resin has a shelf life of about 6 months if it has been opened and 1 year if it is still factory vacuum sealed.