What are your Nitrate and Phosphate numbers?
I recently had this issue and found that while Phosphates were in an acceptable range, Nitrates were ZERO.
I dosed neo-nitro to get Nitrates up. It was gone in about 10 days.
To further make the point, Cyanobacteria can assimilate free nitrogen gas and convert it to ammonia in a process called “nitrogen fixation”.
For this reason, opportunistic algae’s like Cyanobacteria & Dinoflagellets flourish when inorganic nitrogen & phosphate are limited.
Overview
Nitrogen fixation in the marine environment is a critical, steady-state process that converts inert atmospheric nitrogen (N2) into bioavailable ammonia.
These processes are primarily driven by microorganisms called diazotrophs. It supports ocean productivity, particularly in nutrient-poor (oligotrophic) regions, by providing new nitrogen that fuels phytoplankton growth. Key nitrogen fixers include cyanobacteria like
Trichodesmium and, surprisingly, non-cyanobacterial diazotrophs on marine

particles.
Key Nitrogen-Fixing Organisms
While traditionally attributed to a few cyanobacteria, the diversity of marine nitrogen-fixers is broader than previously thought.
- Trichodesmium
: A filamentous, colony-forming cyanobacterium responsible for nearly half of global marine nitrogen fixation, often forming large surface blooms.
- Unicellular Cyanobacteria (UCYN)
: Small, single-celled groups (UCYN-A, B, and C) that are widespread and often equal or exceed Trichodesmium in activity.
- Symbiotic Diazotrophs
: Organisms like
Richelia
that live inside or on the shells of diatoms, providing nitrogen in exchange for carbon and protection.
- Non-Cyanobacterial Diazotrophs (NCDs)
: Diverse heterotrophic bacteria and archaea that fix nitrogen in the dark, on sinking particles, or in the deep sea.
- Nitroplasts
: A recently discovered nitrogen-fixing organelle in certain marine algae (
Braarudosphaera bigelowii
), representing an evolutionary transition from symbiont to organelle.
Environmental Drivers and Limitations
Nitrogen fixation is an energy-intensive process regulated by several physical and chemical factors.
- Nutrient Availability: The enzyme nitrogenase requires high amounts of iron (Fe)and phosphorus (P); limited supply of these elements often constrains fixation rates.
- Oxygen Levels: Nitrogenase is inhibited by oxygen; diazotrophs use strategies like temporal separation (fixing at night) or specialized cells (heterocysts) to protect the enzyme.
- Temperature: Most active diazotrophs prefer warm tropical and subtropical waters, though fixation has been detected in colder polar regions.
