How large is your refugium? How much are you harvesting every week? Do you know your alk swing between night and day ? You say your not dosing any DOC but - you use the black bucket and have - as I understand a good growing chaeto refugium. You may get in DOC from sources that you not realize directly. The black bucket have increased KH concentration and some other "good" things as they state.
A calc reactor produce alkalinity all over the day but the consumption is not equal during night and day. In my aquarium - I need to add around 84 % of the alkalinity between 12:00 and 00:00 and around 16 % during 00:00 to 12:00 in order to get a max variation of around 0.3 dKH. For the moment I dial it in in order to get a constant alkalinity
Sincerely Lasse