Randy Holmes-Farley
Reef Chemist
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If they are immeasurable then how do we know that they are there and if they are immeasurable then How do we know that they are harmful?
Water changes are insurance against unknown problems accumulating. People do a great many things, both in and outside of the hobby to avoid potential problems without any evidence that they will suffer the problem if one does not mitigate it.
We know many inorganic and organic compounds are toxic to marine creatures. That's exactly why many of them are synthesized by other marine creatures in the first place.
I cannot prove any specific toxins accumulate, since as far as I know no one has ever looked for any such toxins, but it is demonstrated that organic material in general accumulate in reef tanks, so I'm not sure why one would assume all of those accumulating organics are benign.